Angewandte Chemie

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The 3 studies conceal the advances within the chemistry and biology of withanolides during the last sixteen years, overview the chemistry and biology of the rocaglamide-type derivatives and similar compounds, with emphasis on their structural variety, biosynthesis, pharmacological value and overall synthesis, and summarize the large chemistry and biology experiences on a ordinary product, that have led to a unique remedy licensed world wide.

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Soc. [London] 1962, 3880. , and C. S. M a r v e l : Polybenzimidazoles. III. J. Polymer Sci. A 2, 2559 (1964). Rausch, M . D. : Organometallic-Complexes. VII. Studies on Mercuriferrocenes. J. Org. Chem. 28, 3337 (1963). -- M . Vogel, and H . Rosenberg: Ferrocene: A Novel Organometallic Compound. J. Chem. Educat. 34, 268 (1957). , F . W i d m e r u. ,4. v. Schulthess : l~Iber neue, d u t c h Polydienaddition hArtbare Kunststoffe. Kunststoffe 53, 509 (1963). Richards, J . t~. A . H i l l : ~-Metalloccnyl carbonium Ions.

Chem. 28, 3337 (1963). -- M . Vogel, and H . Rosenberg: Ferrocene: A Novel Organometallic Compound. J. Chem. Educat. 34, 268 (1957). , F . W i d m e r u. ,4. v. Schulthess : l~Iber neue, d u t c h Polydienaddition hArtbare Kunststoffe. Kunststoffe 53, 509 (1963). Richards, J . t~. A . H i l l : ~-Metalloccnyl carbonium Ions. J. Amer. Chem. Soc. 81, 3484 (1959). , K . , C. ] . Michejda, and P. `4. Kittle : 1,2-Diferrocenylethane from a n Unusual Reaction. J. Amer. Chem. Soc. 87, 3162 (1959). Rosenberg, H..

1 6 7 ,, CHa - s . . 9 . . R~ CHa-- ++++ Br-oCH_~O-qH~-- +d-d-+ . l1 . 12 CH~-- . ++++ + +++ +++ H~CH--~ H~C/ ~ (CH~)~C-(CHa)aC-- -- CH~-- + CaH~-- + + + ~ . Wirksamkeit -- ~ . H~C=C--CH~-- ++++ ] C~ 264 ,, H~C-- --- Carbamatc als Agrarchemikalien Die bei den bisher besprochenen N-Arylcarbamaten (Tabelle 5) gefundenen Gesetzm~iBigkeiten sind auch bei den N-Alkyl-Derivaten gtiltig. So ffihrt steigende Kohlenstoffzahl des aliphatischen Substituenten zu abnehmender Wirksamkeit (Substanzen 4, 5, 6), w~thrend unges/ittigte Alkylreste die Aktivit/it erh6hen (Substanz 11).

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